Hydroformylation reactions of the trans-Mo(CO)4(p-C5NH4SO3NA)2 complex in biphasic medium
Fecha
2008-10-12Autor
Palabras Clave
Biphasic catalysis, Hydroformylation, Naphtha, Molybdenum complexMetadatos
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Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex,
(trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1-
hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100ºC,
syngas total pressure = 600 psi, pH2/pCO = 1). Complex (1) showed good activity
favoring the linear aldehyde. Likewise as other organic olefin substrates and with
synthetic and real naphtha, good conversions to oxygenated products were
obtained.
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Correo Electrónico | suarez@ula.ve fontal@ula.ve, bfontal@hotmail.com reyes@ula.ve bellandi@ula.ve ricardo@ula.ve cancines@ula.ve fonsy@ula.ve irc@cantv.net |
Editor | Akadémiai Kiadó, Budapest and Springer, Dordrecht |
Descripción | Artículo Publicado en React.Kinet.Catal.Lett. Vol. 94, No. 1, 27−34 (2008) |